Four-component benzyne coupling reactions: a concise total synthesis of dehydroaltenuene B.
Org Lett, 2008/9/04;10(17):3833-5.
Soorukram D[1], Qu T, Barrett AG
Affiliations
PMID: 18672878DOI: 10.1021/ol8015435
Impact factor: 6.072
Abstract
A four-component coupling reaction of 3,5-dimethoxybenzyne with 2-methyl-2-cyclohexenylmagnesium chloride, carbon dioxide, and iodine was utilized as a key step in the first total synthesis of dehydroaltenuene B.
MeSH terms
Ascomycota; Benzene Derivatives; Cyclohexenes; Lactones; Magnesium; Mycotoxins; Organometallic Compounds
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