The involvement of superoxide anions in the autoxidation of various cofactors of cysteamine-oxygenase.

Mol Cell Biochem, 1975/12/31;9(3):149-54.

Dupré S, Federici G, Santoro L, Rossi Fanelli MR, Cavallini D

PMID: 172779

Impact factor: 3.842

Abstract
The reduction of tetranitroblue tetrazolium with cysteamine, mediated by a number of dyes, elemental sulphur, elemental selenium and selenide, under aerobic conditions, was inhibited to various extent upon addition of superoxide dismutase. A strict parallelism between the ability to produce O2- ions and the property of those compounds to act as cofactors for cysteamine-oxygenase, to yield hypotaurine, has been observed. Based on the fact that the autoxidation of cysteamine also gives rise to O2- formation, though to a minor extent, we propose a mechanism for cysteamine-oxygenase action. This mechanism was derived from the data obtained in the model system studied.
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